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Cyclohexanone derivatives and preparation thereof

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专利名称:Cyclohexanone derivatives and preparation

thereof

发明人:Torii, Sigeru,Uneyama, Kenji,Onishi,

Takashi,Fujita, Yoshiji,Ishiguro,Michihiro,Nishida, Takashi

申请号:EP81104092.2申请日:19810527公开号:EP0041656A2公开日:19811216

摘要:Novel cyclohexanone derivatives of general formula: (wherein R is ahydrocarbon group of 1 to 15 carbon atoms) and new cyclohexanone derivatives ofgeneral formula: (wherein R' and R each is a hydrocarbon group of 1 to 15 carbon atoms)are produced by an electrooxidative coupling of 1,3-cyclohexanedione with a vinyl etherof generat formula: (wherein R is as defined above) in the presence or absense of analcohol of general formula: (wherein R is as defined above). These new cyclohexanonederivatives can be easily converted to N-substituted or unsubstituted-4-oxo-4,5,6,7-tetrahydroindoles, which are of value as intermediates for the production of N-substituted or unsubstituted-4-hydroxyindoles and, thence, to pindolol and its analogs.

申请人:KURARAY CO., LTD.

地址:1621 Sakazu Kurashiki-City Okayama Prefecture 710 JP

国籍:JP

代理机构:Müller-Boré & Partner Patentanwälte

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